George R. Brubaker and P. Beverley P. Phipps (Eds.)'s Corrosion Chemistry PDF

By George R. Brubaker and P. Beverley P. Phipps (Eds.)

Content material: Corrosion : the main common challenge of fabrics technology / Donald Tuomi -- Electrochemical suggestions in corrosion stories / Francis M. Donahue -- High-temperature corrosion / J. Bruce Wagner, Jr. -- Ionic and digital conduction in nonmetallic stages / John W. Patterson -- Dissolution of iron / Morris Cohen -- Ferrous passivation / V. Brusic -- Corrosion of valve metals -- J.E. Draley -- The function of water in atmospheric corrosion / P.B.P. Phipps and D.W. Rice -- Corrosion inhibition and inhibitors / Rudolf H. Hausler -- Stress-corrosion cracking / J.C. Scully -- business difficulties : cooling water and cooling-water therapy / J. Fred Wilkes -- High-temperature corrosion in coal gasification vegetation / V.L. Hill, D. Yates, and B.A. Humphreys

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Electrochemical D O N A H U E μ γ 41 Techniques = μ£ + RT £n a (9) y I n s e r t i n g E q u a t i o n s 8 and 9 in 7 and r e a r r a n g i n g Φ Y ο = (1/ν^)Σν μ£ + (RT/v F)£n(n(a ) ) γ e y (10) I t c a n be shown t h a t φ° = (l/v F)Zv ° e (11) yy where φ° is t h e s t a n d a r d e l e c t r o d e p o t e n t i a l o f t h e r e a c t i o n . Tabulated values o f standard e l e c t r o d e poten­ t i a l s r e l a t i v e t o SHE f o r many e l e c t r o c h e m i c a l r e a c t ­ i o n s o f i n t e r e s t in c o r r o s i o n a r e a v a i l a b l e (£) I n ­ s e r t i n g Equation 1 Φ Y ο = φ° + (RT/v F)£n(II(a ) ) e Y (12) E q u a t i o n 12 may be used t o compute e q u i l i b r i u m electrode potentials f o r electrochemical reactions.

A) I f t h e o n l y i n f o r m a t i o n a v a i l a b l e a r e t h e a c t i v i t i e s o f - h y d r o g e n i o n (10 ) and c u p r i c i o n (10~ ) , can c o r r o s i o n o c c u r ? 2 is in e q u i ­ l i b r i u m w i t h t h e s o l u t i o n in p a r t " a " , can c o r r o s i o n o c c g r ? _η c) I f f e r r o u s (a=10 ) and f e r r i c (a=10 ) i o n s a r e c o n t a m i n a n t s o f t h e s o l u t i o n in p a r t " a " , can c o r r o s i o n o c c u r ? 553X10 c a l / m o l e o f Cu T h e r e f o r e , c o r r o s i o n c a n n o t o c c u r by postulated reaction.

Equat i o n 36. T h i s dashed l i n e p r e d i c t s c u r r e n t d e n s i t i e s w h i c h exceed t h e r a t e o f mass t r a n s p o r t - an i m p o s s i b i l i t y . The v e r t i c a l ( e l e c t r o d e p o t e n t i a l i n d e p e n d e n t ) l i n e represents the l i m i t i n g current density for the p r o c e s s . ; ACS Symposium Series; American Chemical Society: Washington, DC, 1979. 0 10 l_ 100 2 CURRENT DENSITY (mA/cm ) Figure 7. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1979.

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